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Western world
Wrought iron has been used for many centuries, and is the "iron" that is referred to throughout Western history. The other form of iron, cast iron, was in use in China since ancient times but was not introduced into Western Europe until the 15th century; even then, due to its brittleness, it could be used for only a limited number of purposes. Throughout much of the Middle Ages iron was produced by the direct reduction of ore in manually operated bloomeries, although waterpower had begun to be employed by 1104.
The raw material produced by all indirect processes is pig iron. It has a high carbon content and as a consequence it is brittle and could not be used to make hardware. The osmond process was the first of the indirect processes, developed by 1203, but bloomery production continued in many places. The process depended on the development of the blast furnace, of which medieval examples have been discovered at Lapphyttan, Sweden and in Germany.
The bloomery and osmond processes were gradually replaced from the 15th century by finery processes, of which there were two versions, the German and Walloon. They were in turn replaced from the late 18th century by puddling, with certain variants such as the Swedish Lancashire process. Those, too, are now obsolete, and wrought iron is no longer manufactured commercially.
China
During the Han dynasty, new iron smelting processes led to the manufacture of new wrought iron implements for use in agriculture, such as the multi-tube seed drill and iron plough. In addition to accidental lumps of low-carbon wrought iron produced by excessive injected air in ancient Chinese cupola furnaces. The ancient Chinese created wrought iron by using the finery forge at least by the 2nd century BC, the earliest specimens of cast and pig iron fined into wrought iron and steel found at the early Han Dynasty (202 BC – 220 AD) site at Tieshengguo.Pigott speculates that the finery forge existed in the previous Warring States period (403–221 BC), due to the fact that there are wrought iron items from China dating to that period and there is no documented evidence of the bloomery ever being used in China.The fining process involved liquifying cast iron in a fining hearth and removing carbon from the molten cast iron through oxidation. Wagner writes that in addition to the Han Dynasty hearths believed to be fining hearths, there is also pictoral evidence of the fining hearth from a Shandong tomb mural dated 1st to 2nd century AD, as well as a hint of written evidence in the 4th century AD Daoist text Taiping Jing.